Single-Site Zeolite-Anchored Organoiridium Carbonyl Complexes: Characterization of Structure and Reactivity by Spectroscopy and Computational Chemistry.
Single-Site Zeolite-Anchored Organoiridium Carbonyl Complexes: Characterization of Structure and Reactivity by Spectroscopy and Computational Chemistry.
Claudia Martínez-Macias,Mingyang Chen,D. Dixon,B. Gates
2015 · DOI: 10.1002/chem.201501277
Chemistry · 27 Citations
TLDR
A family of HY zeolite-supported cationic organoiridium carbonyl complexes was formed by reaction of Ir(CO)2 (acac) (acAC=acetylacetonate) to form supported Ir( CO)2 complexes, which were treated at 298 K and 1 atm with flowing gas-phase reactants.