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Liquids at Large Negative Pressures: Water at the Homogeneous Nucleation Limit

Q. Zheng,D. Durben,G. Wolf,C. Angell

1991 · DOI: 10.1126/science.254.5033.829
Science · 386 Citations

TLDR

An isochoric cooling method for obtaining unprecedented tensions on liquids was used to determine the homogeneous nucleation limit for stretching of water at a variety of water densities, and confirms the existence of a density maximum at 42�C and –140 megapascals and greatly strengthens the basis for Speedy's conjecture of a reentrant spinodal for water.