Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations.
Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations.
Baihua Ye,N. Cramer
2015 · DOI: 10.1021/acs.accounts.5b00092
Accounts of Chemical Research · 599 Citations
TLDR
A side- and back-wall concept to enforce chirality transfer onto the central metal atom is introduced and Cp(x) derivatives hold promise as powerful steering ligands for further transition-metals used in asymmetric catalysis.