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Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.

C. G. Newton,Shou‐Guo Wang,Caio C. Oliveira,N. Cramer

2017 · DOI: 10.1021/acs.chemrev.6b00692
Chemical Reviews · 708 Citations

TLDR

This analysis comprehensively review all asymmetric transition-metal-catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emphasis on the nature of stereochemistry generation.