Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.
Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.
C. G. Newton,Shou‐Guo Wang,Caio C. Oliveira,N. Cramer
2017 · DOI: 10.1021/acs.chemrev.6b00692
Chemical Reviews · 708 Citations
TLDR
This analysis comprehensively review all asymmetric transition-metal-catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emphasis on the nature of stereochemistry generation.
