Nano-Sized Calcium Copper Titanate for the Fabrication of High Dielectric Constant Functional Ceramic–Polymer Composites

A novel calcium copper titanate (CaCu3Ti4O12)–polyvinylidene fluoride composite (CCTO@PVDF) with Cu-deficiency was successfully prepared through the molten salt-assisted method. The morphology and structure of polymer composites uniformly incorporated with CCTO nanocrystals were characterized. At the same volume fraction, the CCTOs with Cu-deficiency displayed higher dielectric constants than those without post-treatment. A relatively high dielectric constant of 939 was obtained at 64% vol% CCTO@PVDF content, 78 times that of pure PVDF. The high dielectric constants of these composites were attributed to the homogeneous dispersion and interfacial polarization of the CCTO into the PVDF matrix. These composites also have prospective applications in high-frequency regions (106 Hz). The enhancement of the dielectric constant was predicted in several theoretical models, among which the EMT and Yamada models agreed well with the experimental results, indicating the excellent distribution in the polymer matrix.